0001349409-07-000014 Sample Contracts

SECURITY AGREEMENT
Security Agreement • March 5th, 2007 • Paincare Holdings Inc • Services-misc health & allied services, nec • Colorado

This SECURITY AGREEMENT (this “Agreement”) is made and entered into as of the 22nd day of February, 2007, by and among by and among CHRISTOPHER J. CENTENO, M.D.(“Centeno”), JOHN SCHULTZ, M.D. (“Schultz”), CHRISTOPHER J. CENTENO, M.D., P.C., a Colorado professional corporation (the “Original Practice) and CENTENO SCHULTZ, INC., a Colorado corporation (“CSI”, and collectively with the Original Practice, Centeno and Schultz, the “Debtor” having the address 11080 Circle Point Road, Suite 140, Westminster, Colorado 80020), and PAINCARE ACQUISITION COMPANY XXI, INC., a Florida corporation having the address 1030 North Orange Avenue, Suite 105, Orlando, Florida 32801 (the “Secured Party”).

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SETTLEMENT AGREEMENT
Settlement Agreement • March 5th, 2007 • Paincare Holdings Inc • Services-misc health & allied services, nec • Colorado

This Settlement Agreement (“Settlement Agreement”) is entered into as of February 22, 2007, by and among PainCare Holdings, Inc. (“PainCare”) and PainCare Acquisition Company XXI, Inc. (“PainCare Sub” and together with PainCare, the “Sellers”) on the one hand, Christopher J. Centeno, M.D., P.C. (the “Original Practice”), Therapeutic Management, Inc. (“TMI”), Christopher J. Centeno, M.D. (“Centeno”), John Schultz, M.D. (“Schultz”), and Centeno Schultz, Inc. (“CSI”, and together with the Original Practice, Centeno, Schultz and TMI, the “Purchasers”). Each of the Sellers and the Purchasers may be referred to herein as a “Party” or collectively as the “Parties.”

SELLERS’ GENERAL RELEASE
Sellers’ General Release • March 5th, 2007 • Paincare Holdings Inc • Services-misc health & allied services, nec

This General Release (“Release”) is being made and delivered by PAINCARE HOLDINGS, INC., a Florida corporation (“PainCare”), and PAINCARE ACQUISITION COMPANY XXI, INC. a Florida corporation (“PainCare Sub”), (collectively the “Releasors”), as of this 22nd day of February, 2007 (the “Effective Date”), with the express intention of binding the Releasors.

MANAGEMENT SERVICES TERMINATION AGREEMENT
Management Services Termination Agreement • March 5th, 2007 • Paincare Holdings Inc • Services-misc health & allied services, nec

This MANAGEMENT SERVICES TERMINATION AGREEMENT (the “Termination Agreement”) is made this 22nd day of February, 2007 (the “Effective Date”), by and among PainCare Acquisition Company XXI, Inc., a Florida corporation (“Manager”), Centeno Schultz, Inc., a Colorado corporation (“Provider Network”), Christopher J. Centeno, M.D. and John Schultz, M.D., each a shareholder of Provider Network (collectively, “Shareholder”). Manager, Provider Network and Shareholders are sometimes referred to herein singly as a “Party” and collectively as the “Parties.”

TERMINATION AGREEMENT
Termination Agreement • March 5th, 2007 • Paincare Holdings Inc • Services-misc health & allied services, nec

This TERMINATION AGREEMENT (the “Termination Agreement”) is made this 22nd day of February, 2007 (the “Effective Date”), by and among PainCare Acquisition Company XXI, Inc., a Florida corporation (“PainCare Sub”), PainCare Holdings, Inc., a Florida corporation (“PainCare”), Centeno Schultz, Inc., a Colorado corporation (“New Practice”), Christopher J. Centeno, M.D., P.C., a Colorado professional corporation (“Original Practice”), Christopher J. Centeno, M.D., (“Centeno”) and John Schultz, M.D. (“Schultz”). PainCare Sub, PainCare, New Practice, Original Practice, Centeno and Schultz are sometimes referred to herein singly as a “Party” and collectively as the “Parties.”

PURCHASERS’ GENERAL RELEASE
Purchasers’ General Release • March 5th, 2007 • Paincare Holdings Inc • Services-misc health & allied services, nec

This General Release (“Release”) is being made and delivered by CENTENO SHULTZ, INC., a Colorado corporation (“CSI”), THERAPEUTIC MANAGEMENT, INC., a Colorado corporation (“TMI”), CHRISTOPHER J. CENTENO, M.D., P.C., a Colorado professional corporation (“Original Practice”), CHRISTOPHER J. CENTENO, M.D. (“Centeno”) and JOHN SCHULTZ, M.D. (“Shultz”), (collectively the “Releasors”), as of this 22nd day of February, 2007 (the “Effective Date”), with the express intention of binding the Releasors.

PLEDGE AGREEMENT
Pledge Agreement • March 5th, 2007 • Paincare Holdings Inc • Services-misc health & allied services, nec • Florida

THIS PLEDGE AGREEMENT (the “Pledge Agreement”) is dated and effective as of February 22, 2007 by and among CHRISTOPHER J. CENTENO, M.D.(“Centeno”), JOHN SCHULTZ, M.D. (“Schultz”), CHRISTOPHER J. CENTENO, M.D., P.C., a Colorado professional corporation (the “Original Practice) and CENTENO SCHULTZ, INC., a Colorado corporation (“CSI”, and collectively with the Original Practice, Centeno and Schultz, “Pledgor”), and PAINCARE ACQUISITION COMPANY XXI, INC., a Florida corporation (“Creditor”).

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