0001131312-06-000100 Sample Contracts

N E T W O R K 1 F I N A N C I A L S E C U R I T I E S, I N C.
Zion Oil & Gas Inc • September 14th, 2006 • Oil & gas field exploration services • New York

This agreement amends and restates that certain amended and restated underwriting agreement originally dated December 2, 2005 and amended March 15, April 24, May 23, and July 19, 2006 between Zion Oil & Gas, Inc. (the "Company"), a Delaware corporation, and us (the "Underwriter") in connection with the offering and sale through Network 1 Financial Services, Inc. (the "Underwriter") and other broker-dealers ("Placement Agents") of up to 2,000,000 shares of the Company's $.01 par value common stock (the "Shares") for $7.00 per Share. The offering of the Shares is further described in the Registration Statement on Form SB-2 filed on January 25, 2006 (as subsequently amended) with the Securities and Exchange Commission (the "SEC").

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EMPLOYMENT AGREEMENTS WITH EXECUTIVE OFFICERS
Personal Employment Agreement • September 14th, 2006 • Zion Oil & Gas Inc • Oil & gas field exploration services

This Personal Employment Agreement (the "Agreement") is entered into as of the 1st day of January 2004 (the "Effective Date"), by and among Zion Oil & Gas, Inc., a Delaware corporation with offices at 6510 Abrams Road, Suite 300, Dallas, Texas, (in its own name and as successor in interest of Zion Oil & Gas, Inc., a Florida Corporation, the "Company") and John M. Brown of 600 St. Emelion Ct., Irving, Texas, (the "Employee").

RINBERG-BROWN VOTING AGREEMENT STOCKHOLDERS' AND VOTING AGREEMENT
Stockholders' and Voting Agreement • September 14th, 2006 • Zion Oil & Gas Inc • Oil & gas field exploration services • Texas

This STOCKHOLDERS' AND VOTING AGREEMENT, effective as of the first day of November, 2005, is made by and among Zion Oil & Gas, Inc., a Delaware corporation (the "Company"), John M. Brown ("Brown") and Richard J. Rinberg (the "Stockholder).

STOCKHOLDERS' AND VOTING AGREEMENT (With Ralph DeVore)
Stockholders' and Voting Agreement • September 14th, 2006 • Zion Oil & Gas Inc • Oil & gas field exploration services • Texas

This STOCKHOLDERS' AND VOTING AGREEMENT, dated as of the 9th day of July, 2003, is made by and among Zion Oil & Gas, Inc., a Delaware corporation (the "Company"), Ralph DeVore ("DeVore"), and the stockholders of the Company listed on Schedule A, and such other stockholders of the Company who may become parties to this Agreement.

STOCKHOLDERS' AND VOTING AGREEMENT (With John M. Brown)
Stockholders' and Voting Agreement • September 14th, 2006 • Zion Oil & Gas Inc • Oil & gas field exploration services • Texas

This STOCKHOLDERS' AND VOTING AGREEMENT, dated as of the 9th day of July, 2003, is made by and among Zion Oil & Gas, Inc., a Delaware corporation (the "Company"), John M. Brown ("Brown"), and the stockholders of the Company listed on Schedule A, and such other stockholders of the Company who may become parties to this Agreement.

Form of) STOCKHOLDERS' AND VOTING AGREEMENT (With Executive Officer)
Stockholders' and Voting Agreement • September 14th, 2006 • Zion Oil & Gas Inc • Oil & gas field exploration services • Texas

This STOCKHOLDERS' AND VOTING AGREEMENT, dated as of the 15th day of December, 2005, is made by and among Zion Oil & Gas, Inc., a Delaware corporation (the "Company"), Executive Officer ("Officer") and the stockholders of the Company listed on Schedule A, and such other stockholders of the Company who may become parties to this Agreement.

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