Coordination Polymerization definition

Coordination Polymerization means a metal mediated polymerization that proceeds by a polymerization reaction other than free radical, controlled free radical, and carbocationic mechanisms. For the Vinyl Chloride Field and Polar Comonomer within Exhibit A, Coordination Polymerization mechanisms will be determined by examination of the effect of the metal on the relative copolymerization rate constants: i.e., monomer selectivities. In controlled free radical and free radical polymerizations the metal is not involved in the propagation steps and therefore it does not affect the microstructure, sequence distributions, or comonomer content in a copolymerization. The presence and structure of the active metal complex in a Coordination Polymerization must have a direct and significant effect on the microstructure and comonomer content of the polymer because the metal is involved in each propagation step during the polymerization. A test for Coordination Polymerization would be to run two derivatives of the catalyst family (e.g. one with bulky ligands, one less bulky) in a copolymerization; changes in composition of the polymer will be indicative of Coordination Polymerization. Tests comparing the composition and r1/r2 of polymers obtained using conventional free radical initiators with those obtained using the “catalyst” will also be performed.
Sample 1
Coordination Polymerization means a metal mediated polymerization that proceeds by a polymerization reaction other than free radical, controlled free radical, and carbocationic mechanisms. For the [******] within Exhibit A, Coordination Polymerization mechanisms will be determined by examination of the effect of the metal on the relative copolymerization rate constants: i.e., monomer selectivities. [******].
Sample 1

Examples of Coordination Polymerization in a sentence

  • Coordination Polymerization of Dienes, Allenes, and Methylenecycloalkanes.

  • Highly Stereoselective Coordination Polymerization of β-Myrcene from a Lanthanide-Based Catalyst: Access to Bio-Sourced Elastomers.

  • Coordination Polymerization, Polyolefin types: microstructural classification and analytical Techniques, Catalysts for olefin polymerization, Polymerization kinetics for single- and multiple- site catalysts, Inter- and intra-particle mass and heat transfer resistances, Industrial olefin polymerization reactors, Metallocene polyolefins reactor.

  • Synthesis of Block and Graft Copolymers with Linear Polyethylene Segments by Combination of Degenerative Transfer Coordination Polymerization and Atom Transfer Radical Polymerization.

  • J.C.W. Chien - Coordination Polymerization, Academic Press, New York, 1975.

  • Living Coordination Polymerization of a Six-Five Bicyclic Lactone to Produce Completely Recyclable Polyester.

Related to Coordination Polymerization

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